UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013)
Lec 22. Molecular Structure & Statistical Mechanics -- The Boltzmann Distribution.
View the complete course: ../courses/chem_131b_molecular_structure_and_elementary_statistical_mechanics.html
Instructor: Rachel Martin, Ph.D.
License: Creative Commons BY-NC-SA
Terms of Use: ../info.
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Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules.
Recorded on March 6, 2013.
Index of Topics:
03:27 - 20: The Boltzmann Distribution
05:23 - NMR Population Differences
06:14 - What is the Population Difference?
10:34 - Statistical Mechanics
12:38 - Statistical Mechanics: Ensemble
15:32 - Statistical Mechanics: Ensemble, Slide 2
17:14 - Conformational Ensemble
18:09 - Conformational Ensemble, Slide 2
18:47 - Statistical Mechanics
21:08 - Statistical Mechanics, Slide 2
24:26 - Weights of Configurations
27:47 - Weights of Configurations, Slide 2
30:07 - Dominant Configuration
33:59 - Dominant Configuration, Slide 2
34:58 - Dominant Configuration, Slide 3
38:18 - Dominant Configuration, Slide 4
39:48 - Dominant Configuration, Slide 5
41:17 - Relative Populations
43:05 - Rotational Spectrum of HCl
Required attribution: Martin, Rachel. Molecular Structure & Statistical Mechanics 131B (UCI OpenCourseWare: University of California, Irvine), ../courses/chem_131b_molecular_structure_and_elementary_statistical_mechanics.html. [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License.
